Course Details
Subject {L-T-P / C} : CY4703 : Physical Chemistry Laboratory { 0-0-3 / 2}
Subject Nature : Practical
Coordinator : Prof. Usharani Subuddhi
Syllabus
Chemical Kinetics: Alkaline hydrolysis of ethylacetate Kinetics of iodination of acetone by (i) Volumetry and (ii) Spectrophotometry Polarimetric determination of concentration of unknown sugar solution and Study of kinetics of inversion of sucrose.
Thermodynamic Properties of Solutions: Detremination of the dimerisation constant of benzoic acid in benzene medium by partition method Determination of equilibrium constant of the reversible reaction KI + I2 ? KI3 Determination of Co-ordination number of copper in copper-amine complex by distribution method.
Phase Equilibrium: Determination of critical solution temperature of two partially miscible liquids Effect of electrolyte on the critical solution temperature of two partially miscible liquids Phase diagram of two component simple eutectic system,
Simultaneous estimation of Manganese and Chromium in a solution of K2Cr2O7 and KMnO4 Job’s continuous variation method to know the stoichiometry of metal complexes, Determination of indicator constant (pKIn) of an indicator.
Course Objectives
- This course is intended to acquaint the students with the practice of experimental physical chemistry
Course Outcomes
Students will be able to apply the principles of thermodynamics, kinetics, spectroscopy and various other topics presented in the physical chemistry courses, in some illustrative experiments.
Essential Reading
- B. Viswanathan and P. S. Raghavan, Practical Physical Chemistry, Viva Books Pvt. Ltd.
- B. Behera, Experimental Physical Chemistry, Tata McGraw Hill
Supplementary Reading
- Halpern, A. M. McBane, G. C., Experimental Physical Chemistry: A Laboratory Text Book, W. H. Freeman
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